Product classification

HS code for PFC mixtures: 3827.32

Mixtures containing halogenated methane, ethane, propane, containing hydrochlorofluorocarbons (HCFCs), perfluorocarbons (PFCs) or hydrofluorocarbons (HFCs) or not, not chlorofluorocarbons (CFCs), containing substances of subheadings 2903.71 to 2903.75.

Classification of PFC mixtures under HS 3827.32

The classification of PFC mixtures under HS code 3827.32 is a result of the 2022 amendments to the Harmonized System, which sought to provide greater granularity for substances with high global warming potential. This code specifically addresses mixtures containing halogenated derivatives of methane, ethane, or propane. To be classified here, the mixture must contain hydrochlorofluorocarbons (HCFCs), perfluorocarbons (PFCs), or hydrofluorocarbons (HFCs). Furthermore, it must specifically contain substances listed in subheadings 2903.71 to 2903.75, which include chemicals like chlorodifluoromethane (HCFC-22) or various isomers of tetrachlorofluoroethanes. The classification is driven by General Interpretative Rule (GRI) 1 and 6, focusing on the chemical constituents of the mixture. These products are primarily used in industrial refrigeration systems, air conditioning units, and as specialized solvents. Because these mixtures are often subject to international environmental treaties like the Montreal Protocol, precise classification is mandatory for regulatory compliance and environmental monitoring. The mixtures must not contain chlorofluorocarbons (CFCs) to remain under this specific subheading, as those are categorized under different subheadings within heading 3827. The technical nature of these chemicals requires laboratory analysis to confirm the presence of specific halogenated hydrocarbons before final classification can be determined.

Covers
  • Refrigerant mixtures containing HCFC-22
  • Solvent blends containing perfluorocarbons and hydrochlorofluorocarbons
  • Fire extinguishing preparations containing substances of subheadings 2903.71 to 2903.75
  • Foam-blowing agent mixtures with HFC and HCFC components
Also under 3827.32
  • DuPont Suva MP39
  • Honeywell Genetron 401A
  • Arkema Forane 409A
  • Chemours Freon 22 (as a blend component)

Codes often confused with 3827.32

Common mistake. PFC mixtures are frequently confused with HS code 3824.71 through 3824.79, which were the previous classifications for these mixtures prior to the 2022 HS update. Additionally, they may be misclassified under 2903.71 to 2903.79 if the importer assumes the product is a pure chemical rather than a mixture. Another common error is using 3827.11, which is reserved specifically for mixtures containing chlorofluorocarbons (CFCs).

3827.39Mixtures containing halogenated methane, ethane, or propane; containing hydrochlorofluorocarbons (HCFCs), perfluorocarbons (PFCs) or hydrofluorocarbons (HFCs) or not, but not chlorofluorocarbons (CFCs); n.e.c. in subheading 3827.33827.51Mixtures containing halogenated derivatives of methane, ethane or propane; containing trifluoromethan (HFC-23) or perfluorocarbons (PFCs) but not containing chlorofluorocarbons (CFCs) or hydrochlorofluorocarbons (HCFCs); containing trifluoromethane (HFC-23827.59Mixtures containing halogenated derivatives of methane, ethane or propane; containing trifluoromethan (HFC-23) or perfluorocarbons (PFCs) not containing chlorofluorocarbons (CFCs) or hydrochlorofluorocarbons (HCFCs); other mixtures n.e.c. in subheading 383827.31Mixtures containing halogenated derivatives of methane, ethane or propane; containing hydrochlorofluorocarbons (HCFCs), perfluorocarbons (PFCs) or hydrofluorocarbons (HFCs) or not, but not containing chlorofluorocarbons (CFCs); containing substances of su2903.71Halogenated derivatives of acyclic hydrocarbons containing two or more different halogens; chlorodifluoromethane (HCFC-22)2903.79Halogenated derivatives of acyclic hydrocarbons containing two or more different halogens; n.e.c. in item no. 2903.73827.11Mixtures containing halogenated derivatives of methane, ethane or propane, not elsewhere specified or included; containing chlorofluorocarbons (CFCs), whether or not containing hydrochlorofluorocarbons (HCFCs), perfluorocarbons (PFCs) or hydrofluorocarbon

Top exporters and importers of HS 382732 (the code used for PFC mixtures), 2025

In 2025, the largest exporter of HS 382732 (the code used for PFC mixtures) in UN Comtrade data was China, with 83% of world exports; the largest importer in UN Comtrade data was South Korea, with 84% of world imports. Mexico reports $159M of its heading 3827 imports without product detail (confidential), so it may also belong among the top importers.

Figures cover everything classified under HS 382732, not only PFC mixtures.

Top exporters 2025 ยท share of world exports

  1. 1 China $353K
  2. 2 United States $70K
  3. 3 Belgium $845

World total: $425K Reported figures on UN Comtrade โ†—

Top importers 2025 ยท share of world imports

  1. 1 South Korea $2.0M
  2. 2 United Arab Emirates* ~$245K
  3. 3 Canada $74K

Mexico reports $159M of its heading 3827 imports without product detail (confidential), so it may also belong among the top importers.

World total: $2.4M Reported figures on UN Comtrade โ†—

How these figures are built

109 countries reported 2025 trade to UN Comtrade in HS 2022, and their own totals are used. Countries marked * did not, so their figures add up what other countries recorded trading with them, and their exports are valued at buyers' CIF prices. Those estimates miss trade with other non-reporting countries, so they can be low, and a non-reporting country can rank higher than shown or be missing from the list. World totals add both and leave out trade between two non-reporting countries. Figures are in current US dollars; reported imports are mostly valued CIF and exports FOB, and exports include re-exports. The UN Comtrade links show the underlying records; they can also list a few reporters left out here (regional groups and older HS editions).

Source: UN Comtrade (United Nations Statistics Division), 2025 annual data.

Brazil NCM codes for PFC mixtures

Brazil splits HS 3827.32 into 2 NCM codes. Pick the one that matches your product:

  • 3827.32.10HCFC-22 and chlorotetrafluoroethane blends
  • 3827.32.90Other blends of HCFC-22, -123, -141, -142 or -225

Source: Siscomex NCM table, updated Oct 2026. The Portuguese text on each NCM page is the official one.

Questions about PFC mixtures

What is the HS code for PFC mixtures?

The HS code for PFC mixtures is 382732 (Mixtures containing halogenated methane, ethane, propane; containing hydrochlorofluorocarbons (HCFCs), perfluorocarbons (PFCs) or hydrofluorocarbons (HFCs) or not, not chlorofluorocarbons (CFCs); containing substances of subheadings 2903.71 to 2903.75). The HS code for mixtures containing PFCs, HFCs, or HCFCs, specifically those containing substances of subheadings 2903.71 to 2903.75, is 3827.32.

How do I classify PFC mixtures for customs?

PFC mixtures is classified under HS code 382732 โ€” Mixtures containing halogenated methane, ethane, propane; containing hydrochlorofluorocarbons (HCFCs), perfluorocarbons (PFCs) or hydrofluorocarbons (HFCs) or not, not chlorofluorocarbons (CFCs); containing substances of subheadings 2903.71 to 2903.75. This is a 6-digit subheading level code.

Does this code include pure perfluorocarbons?

No, pure perfluorocarbons are classified as separate chemically defined compounds under Chapter 29, specifically within heading 2903.

Which countries are the top exporters of PFC mixtures (HS 382732)?

In 2025, the top exporters of HS 382732 (the code used for PFC mixtures) in UN Comtrade data were China ($353K, 83% of world exports), the United States ($70K) and Belgium ($845). World exports came to about $425K, adding countries' reported figures and partner-based estimates for those that did not report (UN Comtrade data). Countries that did not report 2025 data are estimated from partner records, which can understate them.

Which countries are the top importers of PFC mixtures (HS 382732)?

In 2025, the top importers of HS 382732 (the code used for PFC mixtures) in UN Comtrade data were South Korea ($2.0M, 84% of world imports), the United Arab Emirates (about $245K) and Canada ($74K). World imports came to about $2.4M, adding countries' reported figures and partner-based estimates for those that did not report (UN Comtrade data). Mexico reports $159M of its heading 3827 imports without product detail (confidential), so it may also belong among the top importers.

Is the HS code for PFC mixtures the same in all countries?

The base HS code 382732 for PFC mixtures is internationally standardized for the first 6 digits across 200+ countries. Individual countries may add additional digits for national tariff lines and specific classifications.

What is the NCM code for PFC mixtures in Brazil?

Brazil splits HS 382732 into 2 NCM codes, so the right one for PFC mixtures depends on the product's details: 3827.32.10 (HCFC-22 and chlorotetrafluoroethane blends), 3827.32.90 (Other blends of HCFC-22, -123, -141, -142 or -225).