HS code · 4-digit heading

HS Code 74.01 – Copper mattes; cement copper (precipitated copper)

What HS 74.01 covers

HS Code 7401 encompasses "Copper mattes; cement copper (precipitated copper)," representing the initial, intermediate products in the copper refining process. Copper mattes are crude, high-sulfur mixtures of copper, iron, and sulfur, typically produced by smelting copper concentrates. They are not directly usable but serve as a crucial feedstock for further pyrometallurgical refining to extract purer copper. Cement copper, also known as precipitated copper, is produced through hydrometallurgical processes where copper ions in solution are reduced and deposited as a relatively pure metal powder or spongy mass. Both forms signify an early stage of copper extraction, positioning this heading as foundational for the entire copper industry within international trade. This classification is vital for customs authorities to distinguish these low-purity intermediates from more refined forms of copper, ensuring correct duties, trade statistics, and regulatory compliance. Historically, the trade of these raw materials has been essential for industrializing nations lacking primary copper resources. This heading falls under Chapter 74 (Copper and articles thereof) and Section XV (Base Metals and Articles of Base Metal), establishing its role as the very first step in the supply chain for primary copper products, before any significant refining or alloying. Its boundaries are defined by the unrefined and intermediate nature of the copper content, clearly separating it from unrefined copper (7402) or refined copper (7403).

Covers
  • Copper matte lumps
  • Granulated copper matte
  • Copper matte in powder form
  • Cement copper powder
  • Precipitated copper concentrate
  • Copper precipitates from leaching
  • Leached copper product
  • Copper-rich precipitates
  • Copper sulfide concentrates (if considered matte-like)
  • Roasted copper concentrates (if still crude, containing significant sulfur)
  • Copper matte bricks
  • Copper matte pellets
  • Hydrometallurgical copper sludge
  • Primary copper precipitates
  • Copper-iron sulfide matte.
Examples

A major mining company in Chile exports thousands of tons of cement copper powder to a large refinery in China, where it is further refined into copper cathodes for electronics manufacturing, utilizing the Pacific trade route. Similarly, a Zambian copper smelter ships bulk quantities of copper matte in large bags to a European processing plant in Belgium via ocean freight, serving as a vital input for their advanced refining operations. In another scenario, a Peruvian mining operation produces copper precipitates from its leaching facilities, which are then sold and transported to a specialized metal processing facility in Germany for further purification and metal recovery, often moving through the Panama Canal.

Subheadings under 74.01 1

Codes often confused with 74.01

Common mistake. A common misclassification involves confusing 7401 with 7402 (Unrefined copper; copper anodes for electrolytic refining) or even 7403 (Refined copper and copper alloys, unwrought). Traders might mistakenly classify blister copper or black copper, which are more processed forms of unrefined copper, under 7401. The distinction lies in the level of processing and purity: 7401 covers the crudest intermediate forms like mattes (sulfide mixtures) and cement copper (precipitated powder), which require significant further refining. Blister copper (7402) is typically 99-99.5% pure, while refined copper (7403) is 99.9% or higher. Misclassifying can lead to incorrect duty rates and regulatory non-compliance, particularly concerning environmental or material sourcing regulations.

Top exporters and importers of HS code 7401, 2025

In 2025, the largest exporter of HS code 7401 in UN Comtrade data was the Philippines, with 25% of world exports; the largest importer in UN Comtrade data was Belgium, with 38% of world imports. Countries that did not report 2025 data are estimated from partner records, which can understate them.

Top exporters 2025 · share of world exports

  1. 1 Philippines $395M
  2. 2 Canada $276M
  3. 3 Finland $228M

World total: $1.6B Reported figures on UN Comtrade ↗

Top importers 2025 · share of world imports

  1. 1 Belgium $804M
  2. 2 South Korea $409M
  3. 3 China $333M

World total: $2.1B Reported figures on UN Comtrade ↗

How these figures are built

109 countries reported 2025 trade to UN Comtrade in HS 2022, and their own totals are used. Countries that did not report are estimated from what other countries recorded trading with them. Those estimates miss trade with other non-reporting countries, so they can be low, and a non-reporting country can rank higher than shown or be missing from the list. World totals add both and leave out trade between two non-reporting countries. Figures are in current US dollars; reported imports are mostly valued CIF and exports FOB, and exports include re-exports. The UN Comtrade links show the underlying records; they can also list a few reporters left out here (regional groups and older HS editions).

Source: UN Comtrade (United Nations Statistics Division), 2025 annual data.

Questions about HS 74.01

What is HS code 7401?

HS code 7401 is a 4-digit heading in the Harmonized System that covers: Copper mattes; cement copper (precipitated copper). HS Code 7401 encompasses "Copper mattes; cement copper (precipitated copper)," representing the initial, intermediate products in the copper refining process. Copper mattes are crude, high-sulfur mixtures of copper, iron, and sulfur, typically produced by smelting copper concentrates. They are not directly usable but serve as a crucial feedstock for further pyrometallurgical refining to extract purer copper. Cement copper, also known as precipitated copper, is produced through hydrometallurgical processes where copper ions in solution are reduced and deposited as a relatively pure metal powder or spongy mass. Both forms signify an early stage of copper extraction, positioning this heading as foundational for the entire copper industry within international trade. This classification is vital for customs authorities to distinguish these low-purity intermediates from more refined forms of copper, ensuring correct duties, trade statistics, and regulatory compliance. Historically, the trade of these raw materials has been essential for industrializing nations lacking primary copper resources. This heading falls under Chapter 74 (Copper and articles thereof) and Section XV (Base Metals and Articles of Base Metal), establishing its role as the very first step in the supply chain for primary copper products, before any significant refining or alloying. Its boundaries are defined by the unrefined and intermediate nature of the copper content, clearly separating it from unrefined copper (7402) or refined copper (7403).

What products fall under HS code 7401?

Copper matte lumps, granulated copper matte, copper matte in powder form, cement copper powder, precipitated copper concentrate, copper precipitates from leaching, leached copper product, copper-rich precipitates, copper sulfide concentrates (if considered matte-like), roasted copper concentrates (if still crude, containing significant sulfur), copper matte bricks, copper matte pellets, hydrometallurgical copper sludge, primary copper precipitates, copper-iron sulfide matte.

What are common misclassifications for HS code 7401?

A common misclassification involves confusing 7401 with 7402 (Unrefined copper; copper anodes for electrolytic refining) or even 7403 (Refined copper and copper alloys, unwrought). Traders might mistakenly classify blister copper or black copper, which are more processed forms of unrefined copper, under 7401. The distinction lies in the level of processing and purity: 7401 covers the crudest intermediate forms like mattes (sulfide mixtures) and cement copper (precipitated powder), which require significant further refining. Blister copper (7402) is typically 99-99.5% pure, while refined copper (7403) is 99.9% or higher. Misclassifying can lead to incorrect duty rates and regulatory non-compliance, particularly concerning environmental or material sourcing regulations.

Which countries are the top exporters of goods under HS code 7401?

In 2025, the top exporters of HS code 7401 in UN Comtrade data were the Philippines ($395M, 25% of world exports), Canada ($276M) and Finland ($228M). World exports came to about $1.6B, adding countries' reported figures and partner-based estimates for those that did not report (UN Comtrade data). Countries that did not report 2025 data are estimated from partner records, which can understate them.

Which countries are the top importers of goods under HS code 7401?

In 2025, the top importers of HS code 7401 in UN Comtrade data were Belgium ($804M, 38% of world imports), South Korea ($409M) and China ($333M). World imports came to about $2.1B, adding countries' reported figures and partner-based estimates for those that did not report (UN Comtrade data). Countries that did not report 2025 data are estimated from partner records, which can understate them.

How is HS code 7401 structured?

HS code 7401 is a 4-digit heading under Chapter 74 of the Harmonized System. The first 2 digits (74) identify the chapter, and digits 3-4 (01) specify the heading. This code contains multiple 6-digit subheadings for precise product classification.